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Adorable! I too would've liked to have seen ponies, but this is still quite cute, especially since it's unclear how much of Twilight's smile comes from the innocent joys of science and how much from the shipping I crowbarred in with all the grace of a half-paralyzed rhino.
I like what you did with Sunset's eyes, implying their shape with only the brows and the bottoms. But the lack of a nose on Sunset give her face a kind of... fish-like look? The shape of the mouth kind of plays into that as well, I think. Other than that, I like how both of their hairstyles are instantly recognizable, and I can easily tell that Sci-Twi is wearing a lab coat despite the simplicity of the sketch.